Biting pierces the skin and allows them to deposit the venom into your body. I suspect one of the others can give a better, more detailed answer than that though!
Most venemous spiders have fangs, which are usually hidden away, but when it catches prey, the spider sticks the fang into the prey’s body. This causes venom to be released from a gland further inside, and that is squeezed down a hollow duct in the middle of the fang and out of a small opening at the end: just like when you get an injection, but less friendly. The venom contains chemicals that paralyse or kill the prey, making it easier for the spider to eat. Some species wrap their prey up in silk first to make things easier. These little ‘parcels’ have their uses: the spiders can take them back for their babies, or give them to potential suitors to woo them. Who needs chocolates and roses?
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